Exploring Metal–Ligand Interactions In Schiff Base Complexes Of Fe (III), Ru (III), Co (II) And Related MetalsID: 3951 Abstract :Schiff Base Ligands Are Widely Used In Coordination Chemistry Due To Their Strong Chelating Ability And Structural Flexibility. In The Present Study, Schiff Base Complexes Of Fe (III), Ru (III), Co (II), And Related Transition Metals Have Been Synthesized And Investigated. The Metal–ligand Interactions Were Analyzed Using Electronic Spectral Data To Understand Their Coordination Behavior And Geometry. The Results Indicate That Schiff Bases Form Stable Complexes Through Coordination Via Azomethine Nitrogen And Other Donor Groups. Fe (III) Complexes Exhibit Octahedral Geometry With High-spin Configuration, While Ru (III) Complexes Show Low-spin Behavior With Significant Charge Transfer Transitions. Co (II) Complexes Predominantly Display Tetrahedral Geometry, Supported By Characteristic Spectral Bands. The Study Highlights The Importance Of Ligand Structure In Influencing Bonding, Geometry, And Stability Of The Complexes, Making Them Useful For Applications In Catalysis And Material Science. Keywords: Schiff Base, Metal–ligand Interaction, Transition Metals, Fe (III), Ru (III), Co (II), Chelation |
Published:22-9-2026 Issue:Vol. 26 No. 9 (2026) Page Nos:320 - 330 Section:Articles License:This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. How to Cite |